Justin Timberlake and Jessica Biel played picture perfect hosts to U.S. presidential candidate Hillary Clinton during a fundraiser at their Los Angeles home on Tuesday (23Aug16).

The superstar couple served as last-minute hosts for a luncheon in support of the former Secretary of State, after Leonardo DiCaprio abruptly pulled out of his duties on Saturday (20Aug16), due to scheduling issues which left him in New York City.

Despite the late notice, Timberlake and Biel managed to pull off a successful star-studded gathering, which even included a photo booth for guests.

The couple took advantage of its hosting duties and invited the Democratic presidential candidate into the booth, and both stars shared the series of four black-and-white photos on Instagram.

In the pictures, Timberlake and Biel flank Clinton, and the threesome get cosy in the small booth, making funny faces and goofing around. The final snap features the pop star and actress puckering their lips up to Clinton, while she gladly accepts their love.

"Look who came over for lunch... #imwithher", Biel added as a caption, while her husband wrote a similar message, saying, "Look WHO DID come over for lunch... Wow. #ImWithHer".

More than 50 guests were welcomed to their home, including fellow co-hosts Jennifer Aniston, Shonda Rhimes, Tobey Maguire and his jeweller wife Jennifer Meyer, and music manager Scooter Braun and his wife Yael, while Jamie Foxx and rumoured girlfriend Katie Holmes were also in attendance.

Clinton arrived in California on Monday (22Aug16), and after sitting down for an interview with U.S. chat show host Jimmy Kimmel, she attended another fundraiser held at the Beverly Hills home of basketball icon Magic Johnson. Among the 500 guests at that event were Samuel L. Jackson and Kristin Davis.

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